Do all ionic liquids need organic cations? Characterisation of [AlCl2nAmide]+ AlCl4  and comparison with imidazolium based systems

Andrew Ballantyne; Andrew Abbott; Karl S Ryder; Hadi Abood

doi:10.1039/C0CC04989A

Do all ionic liquids need organic cations? Characterisation of [AlCl2nAmide]+ AlCl4 and comparison with imidazolium based systems

Andrew Ballantyne, Andrew Abbott, Karl S Ryder, Hadi Abood

Institute for Creative Leather Technologies

Research output: Contribution to Journal › Letter › peer-review

Abstract

The addition of a simple amide to AlCl3 causes the formation of a liquid of the form [AlCl2nAmide]+ AlCl4. The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. This
ionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.

Original language	English
Pages (from-to)	3523-3525
Number of pages	3
Journal	ChemComm
Volume	47
DOIs	https://doi.org/10.1039/C0CC04989A
Publication status	Published - 8 Feb 2011

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title = "Do all ionic liquids need organic cations? Characterisation of [AlCl2nAmide]+ AlCl4 and comparison with imidazolium based systems",

abstract = "The addition of a simple amide to AlCl3 causes the formation of a liquid of the form [AlCl2nAmide]+ AlCl4. The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. Thisionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.",

author = "Andrew Ballantyne and Andrew Abbott and Ryder, {Karl S} and Hadi Abood",

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AU - Ballantyne, Andrew

AU - Abbott, Andrew

AU - Ryder, Karl S

AU - Abood, Hadi

PY - 2011/2/8

Y1 - 2011/2/8

N2 - The addition of a simple amide to AlCl3 causes the formation of a liquid of the form [AlCl2nAmide]+ AlCl4. The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. Thisionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.

AB - The addition of a simple amide to AlCl3 causes the formation of a liquid of the form [AlCl2nAmide]+ AlCl4. The material thus produced is liquid over a wide temperature range, is relatively insensitive to water and has the properties of an ionic liquid. Thisionic liquid is shown to be a suitable medium for the acetylation of ferrocene and the electrodeposition of aluminium and demonstrated that quaternary ammonium cations are not always needed to form ionic liquids.

U2 - 10.1039/C0CC04989A

DO - 10.1039/C0CC04989A

M3 - Letter

SN - 1364-548X

VL - 47

SP - 3523

EP - 3525

JO - ChemComm

JF - ChemComm

ER -

Do all ionic liquids need organic cations? Characterisation of [AlCl2nAmide]+ AlCl4 and comparison with imidazolium based systems

Abstract

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