Immiscible electrolyte systems based on asymmetric hydrophobic room temperature ionic liquids

A.D. Ballantyne; A.K. Brisdon; R.A.W. Dryfe

doi:10.1039/b809148j

Immiscible electrolyte systems based on asymmetric hydrophobic room temperature ionic liquids

A.D. Ballantyne, A.K. Brisdon, R.A.W. Dryfe

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Abstract

The effect on the melting point of the introduction of asymmetry in tetraalkylammonium halide salts has been investigated leading to the synthesis of new, hydrophobic (room temperature) ionic liquids suitable for liquid/liquid electrochemistry; one of these, tri(hexyl)decylammonium tetrakis(pentafluorophenyl)borate, displays the largest electrochemical window observed to date for a biphasic room temperature ionic liquid system.

Original language	English
Journal	Chemical Communications
Issue number	40
DOIs	https://doi.org/10.1039/b809148j
Publication status	Published - 10 Sept 2008

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abstract = "The effect on the melting point of the introduction of asymmetry in tetraalkylammonium halide salts has been investigated leading to the synthesis of new, hydrophobic (room temperature) ionic liquids suitable for liquid/liquid electrochemistry; one of these, tri(hexyl)decylammonium tetrakis(pentafluorophenyl)borate, displays the largest electrochemical window observed to date for a biphasic room temperature ionic liquid system.",

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AU - Dryfe, R.A.W.

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N2 - The effect on the melting point of the introduction of asymmetry in tetraalkylammonium halide salts has been investigated leading to the synthesis of new, hydrophobic (room temperature) ionic liquids suitable for liquid/liquid electrochemistry; one of these, tri(hexyl)decylammonium tetrakis(pentafluorophenyl)borate, displays the largest electrochemical window observed to date for a biphasic room temperature ionic liquid system.

AB - The effect on the melting point of the introduction of asymmetry in tetraalkylammonium halide salts has been investigated leading to the synthesis of new, hydrophobic (room temperature) ionic liquids suitable for liquid/liquid electrochemistry; one of these, tri(hexyl)decylammonium tetrakis(pentafluorophenyl)borate, displays the largest electrochemical window observed to date for a biphasic room temperature ionic liquid system.

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JO - Chemical Communications

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Immiscible electrolyte systems based on asymmetric hydrophobic room temperature ionic liquids

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